Publications
Prof. Dr. Jörg Libuda
Full publications list
Hauner, J.; Buhlmeyer, H.; Steffen, J.; Trzeciak, S.; Taccardi, N.; Wasserscheid, P.; Zahn, D.; Gorling, A.; Libuda, J., Temperature-Dependent Structure Formation in the Wetting Layer of the Ionic Liquid [C2C1Im] [OTf] on Au(111). J. Phys. Chem. C 2024, 128 (9), 3894-3906, https://dx.doi.org/10.1021/acs.jpcc.3c06299.
Buhlmeyer, H.; Talwar, T.; Eschenbacher, R.; Barreto, J.; Hauner, J.; Knorr, L.; Steinruck, H. P.; Maier, F.; Libuda, J., Surface Chemistry of a [C2C1Im] [OTf] (Sub)Wetting Layer on Pt(111): A Combined XPS, IRAS, and STM Study. ACS Appl. Mater. Interfaces 2024, 16 (18), 24063-24074, https://dx.doi.org/10.1021/acsami.4c02239.
Barreto, J.; Fickenscher, G.; Hohner, C.; Ramos, M. I.; Annese, E.; Archanjo, B.; Achete, C. A.; Libuda, J.; Stavale, F., Structural Characterization of Mn3O4 (001) Thin Films and Their Interaction with CO. J. Phys. Chem. C 2024, 128 (36), 14972-14977, https://dx.doi.org/10.1021/acs.jpcc.4c03828.
Zhou, S. Y.; Rehm, V.; Afify, H. A.; Han, Y. F.; Korczak, J.; Szczerbakow, A.; Story, T.; Peng, Z. J.; These, A.; Barabash, A.; Osvet, A.; Brabec, C. J.; Goetz, K.; Unruh, T.; Hilpert, F.; Brummel, O.; Libuda, J.; Heiss, W., Squeezing the Threshold of Metal-Halide Perovskite Micro-Crystal Lasers Grown by Solution Epitaxy. Adv. Funct. Mater. 2024, https://dx.doi.org/10.1002/adfm.202404700.
Simanenko, A.; Samal, P. K.; Hubsch, R.; Skvára, J.; Yang, J. T.; Kastenmeier, M.; Winkler, F.; Skála, T.; Tsud, N.; Mehl, S.; Myslivecek, J.; Brummel, O.; Lykhach, Y.; Libuda, J., Origin of the Low Overpotential for Isopropanol Oxidation on Pt-Ru Electrocatalysts. Acs Energy Letters 2024, https://dx.doi.org/10.1021/acsenergylett.4c01987.
Fickenscher, G.; Sidorenko, N.; Mikulinskaya, K.; Libuda, J., Different Nucleation Mechanisms during Atomic Layer Deposition of HfS2 on Cobalt Oxide Surfaces. ChemRxiv. 2024; https://dx.doi.org/10.26434/chemrxiv-2024-0qn5p.
Yang, J.; Haßfurther, F.; Hilpert, F.; Hussain, Z.; Yang, T.; Taccardi, N.; Wasserscheid, P.; Brummel, O.; Libuda, J., C-C bond cleavage in the electrooxidation of 2,3-butanediol controlled by an ionic liquid modifier. J. Catal. 2024, 435, 115541, https://doi.org/10.1016/j.jcat.2024.115541, Research Data: https://doi.org/10.5281/zenodo.11004536.
Groppe, P.; Reichstein, R.; Carl, S.; Collados, C.C.; Bart-Jan Niebuur, B-J.; Zhang, K. L.; Zubiri, B. A.; Libuda, J.; Kraus, T.; Retzer, R.; Thommes, M.; Spiecker, E.; Wintzheimer, S.; Mandel, K., Catalyst Supraparticles: Tuning the Structure of Spray-dried Pt/SiO2 Supraparticles via Salt-based Colloidal Manipulation to Control their Catalytic Performance. Small 2024, 2310813, https://doi.org/10.1002/smll.202310813. Research Data: https://doi.org/10.5281/zenodo.11092124.
Bilal, D; Zhang, G.R; Baumunk, A. F.; Yang, J. T; Brummel, O; Darge, P; Dworschak, D; Mayrhofer, K. J. J.; Libuda, J; Zhou, X; Wu, M; Spiecker, E; Ledendecker, M; Etzold, B. J. M. Increasing Activity of Trimetallic Oxygen Reduction PtNiMo/C Catalysts Through Initial Conditioning, ChemElectroChem,2024, 2196-0216, http://dx.doi.org/10.1002/celc.202400070. Research Data: https://doi.org/10.5281/zenodo.10557038.
Hauner, J; Buhlmeyer, H; Steffen, J; Trzeciak, S; Taccardi, N; Wasserscheid, P; Zahn, D; Gorling, A; Libuda, Temperature-Dependent Structure Formation in the Wetting Layer of the Ionic Liquid [C2C1Im][OTf] on Au(111), J. Phys. Chem. C, 2024, 3894-3906, http://dx.doi.org/10.1021/acs.jpcc.3c06299 . Research Data: https://doi.org/10.5281/zenodo.10046641 .
Eschenbacher, R; Steffen, J; Farrugia, K; Taccardi, N; Wasserscheid, P; Görling, A; Libuda, J, Reactivity of a model SCILL: Influence of co-adsorbed [C2C1Im][OTf] on the dehydrogenation of dimethylamine on Pt(111), Surface Science, 2024, 1879-2758 http://dx.doi.org/10.1016/j.susc.2024.122453 . Research Data: https://zenodo.org/doi/10.5281/zenodo.10254227.
Eschenbacher, R; Hemauer, F; Franz, E; Leng, AD; Schwaab, V; Waleska-Wellnhofer, NJ; Freiberger, EM; Fromm, L; Xu, T; Görling, A; Hirsch, A; Steinrueck, HP; Papp, C; Brummel, O; Libuda, J, Au-Catalyzed Energy Release in a Molecular Solar Thermal (MOST) System: A Combined Liquid-Phase and Surface Science Study, ChemPhotoChem, 2024, http://dx.doi.org/10.1002/cptc.202300155 , Research Data: https://zenodo.org/doi/10.5281/zenodo.10022604.
Bühlmeyer, H; Talwar, T; Eschenbacher, R; Baretto, J; Hauner, J; Knörr, L; Steinrück, H-P; Maier, F; Libuda, J, Surface chemistry of a [C2C1Im][OTf] (sub-)wetting layer on Pt(111): a combined XPS, IRAS and STM study, ACS Appl. Mater. Interfaces 2024, 16, 18, 24063–24074, https://doi.org/10.1021/acsami.4c02239. Research Data: https://doi.org/10.5281/zenodo.10949205.
Yang, J. T.; Hilpert, F.; Qiu, Y. S.; Franz, E.; Briega-Martos, V.; Cherevko, S.; Mayrhofer, K.; Brummel, O.; Libuda, J., Interactions of the Ionic Liquid C2C1Im DCA with Au(111) Electrodes: Interplay between Ion Adsorption, Electrode Structure, and Stability. J. Phys. Chem. C 2024, 128 (7), 2834-2843, https://dx.doi.org/10.1021/acs.jpcc.3c07122. Research Data: https://zenodo.org/doi/10.5281/zenodo.10571018.
Fusek, L.; Samal, P. K.; Kerestes, J.; Khalakhan, I.; Johánek, V.; Lykhach, Y.; Libuda, J.; Brummel, O.; Myslivecek, J., A model study of ceria-Pt electrocatalysts: stability, redox properties and hydrogen intercalation. Phys. Chem. Chem. Phys., 2024, 26 (3), https://dx.doi.org/10.1039/d3cp03831a. Research Data: https://doi.org/10.5281/zenodo.8231965.
Fusek, L.; Briega-Martos, V.; Minichová, M.; Fromm, L.; Franz, E.; Yang, J. T.; Görling, A.; Mayrhofer, K. J. J.; Wasserscheid, P.; Cherevko, S.; Brummel, O.; Libuda, J., Toward High-Energy-Density Fuels for Direct Liquid Organic Hydrogen Carrier Fuel Cells: Electrooxidation of 1-Cyclohexylethanol. J. Phys. Chem. Lett. 2024, 15 (9), 2529-2536, https://dx.doi.org/10.1021/acs.jpclett.3c03331.
Fusek, L.; Camellone, M. F.; Ronovsky, M.; Kastenmeier, M.; Skála, T.; Samal, P. K.; Tsud, N.; Mehl, S.; Skvára, J.; Dolák, T.; Uvarov, V.; Setvin, M.; Johánek, V.; Fabris, S.; Brummel, O.; Libuda, J.; Myslivecek, J.; Piccinin, S.; Lykhach, Y., Atomistic picture of electronic metal support interaction and the role of water. J. Mater. Chem. A 2024, https://dx.doi.org/10.1039/d3ta06595b. Research Data: https://doi.org/10.5281/zenodo.10229984.
Fickenscher, G.; Steffen, J.; Gorling, A.; Libuda, J., Atomic Layer Deposition of HfS2 on Functionalized Self-Assembled Monolayers on Ordered Oxide Surfaces: A Model Study under UHV Conditions. J. Phys. Chem. C 2024, 128 (2), 798-809, https://dx.doi.org/10.1021/acs.jpcc.3c06772. Research Data: https://zenodo.org/records/11086690.
Mangoufis-Giasin, I.; Fusek, L.; Yang, T.; Khanipour, P.; Brummel, O.; Libuda, J.; Mayrhofer, K. J. J.; Calle-Vallejo, F.; Katsounaros, I., Activity Trends for the Selective Oxidation of 2-Propanol to Acetone on Noble Metal Electrodes in Alkaline Electrolyte. ACS Catal. 2023, 13 (22), 14562-14569, https://dx.doi.org/10.1021/acscatal.3c03423.
Kastenmeier, M.; Franz, E.; Waidhas, F.; Yang, T.; Taccardi, N.; Wasserscheid, P.; Brummel, O.; Libuda, J., Competition of Acetone Reduction and Hydrogen Evolution on Pt Single Crystal Electrodes in the Absence and Presence of the Ionic Liquid C2C1Im OTf. J. Phys. Chem. C 2023, 127 (47), 22975-22983, https://dx.doi.org/10.1021/acs.jpcc.3c06260. Research Data: https://zenodo.org/doi/10.5281/zenodo.8355133.
Hemauer, F.; Krappmann, D.; Schwaab, V.; Hussain, Z.; Freiberger, E. M.; Waleska-Wellnhofer, N. J.; Franz, E.; Hampel, F.; Brummel, O.; Libuda, J.; Hirsch, A.; Steinrück, H. P.; Papp, C., Surface science and liquid phase investigations of oxanorbornadiene/oxaquadricyclane ester derivatives as molecular solar thermal energy storage systems on Pt(111). J. Chem. Phys. 2023, 159 (7), https://dx.doi.org/10.1063/5.0158124. Research Data: https://zenodo.org/doi/10.5281/zenodo.10979754.
Eschenbacher, R.; Hemauer, F.; Franz, E.; Leng, A. D.; Schwaab, V.; Waleska-Wellnhofer, N. J.; Freiberger, E. M.; Fromm, L.; Xu, T.; Görling, A.; Hirsch, A.; Steinrueck, H. P.; Papp, C.; Brummel, O.; Libuda, J., Au-Catalyzed Energy Release in a Molecular Solar Thermal (MOST) System: A Combined Liquid-Phase and Surface Science Study. ChemPhotoChem 2023, https://dx.doi.org/10.1002/cptc.202300155. Research Data: https://zenodo.org/doi/10.5281/zenodo.10022604.
Brummel, O.; Jacobse, L.; Simanenko, A.; Deng, X.; Geile, S.; Gutowski, O.; Vonk, V.; Lykhach, Y.; Stierle, A.; Libuda, J., Chemical and Structural In-Situ Characterization of Model Electrocatalysts by Combined Infrared Spectroscopy and Surface X-ray Diffraction. J. Phys. Chem. Lett. 2023, 14 (39), 8820-8827, https://dx.doi.org/10.1021/acs.jpclett.3c01777. Research Data: https://doi.org/10.5281/zenodo.8327394.
Zhang, K. L.; Reichstein, J.; Groppe, P.; Schoetz, S.; Stockinger, N.; Libuda, J.; Mandel, K.; Wintzheimer, S.; Retzer, T., Molecular and Structural Insights into H2 Indicator Supraparticles: Lowering the Limit of Detection by Tuning Incorporated Catalyst Nanoparticles. Chem. Mater. 2023, 35 (17), 6808-6822, https://dx.doi.org/10.1021/acs.chemmater.3c01105. Research Data: https://doi.org/10.5281/zenodo.8191500.
Danisman, B.; Zhang, G. R.; Baumunk, A. F.; Yang, J. T.; Brummel, O.; Darge, P.; Mayrhoferhttps, K. J. J.; Libuda, J.; Ledendecker, M.; Etzold, B. J. M., Strong Activity Changes Observable during the First Pretreatment Cycles of Trimetallic PtNiMo/C Catalysts. ChemElectroChem 2023, 10 (16), https://dx.doi.org/10.1002/celc.202300109.
Bühlmeyer, H.; Hauner, J.; Eschenbacher, R.; Steffen, J.; Trzeciak, S.; Taccardi, N.; Görling, A.; Zahn, D.; Wasserscheid, P.; Libuda, J., Structure Formation in an Ionic Liquid Wetting Layer: A Combined STM, IRAS, DFT and MD Study of [C2C1Im][OTf] on Au(111). Chem. Eur. J. 2023, https://dx.doi.org/10.1002/chem.202301328.
Zhang, K. L.; Schotz, S.; Reichstein, J.; Groppe, P.; Stockinger, N.; Wintzheimer, S.; Mandel, K.; Libuda, J.; Retzer, T., Supraparticles for naked-eye H-2 indication and monitoring: Improving performance by variation of the catalyst nanoparticles. J. Chem. Phys. 2023, 158 (13), https://dx.doi.org/10.1063/5.0135130.
Simanenko, A.; Kastenmeier, M.; Piliai, L.; Kosto, Y.; Skala, T.; Tsud, N.; Mehl, S.; Vorokhta, M.; Matolinova, I.; Lykhach, Y.; Libuda, J., Probing the redox capacity of Pt-CeO2 model catalyst for low-temperature CO oxidation. J. Mater. Chem. A , 2023, https://dx.doi.org/10.1039/d3ta02507a.
Libuda, J.; Gorling, A., Functional molecular structures on complex oxide surfaces. Surface Science, 2023, 729, https://dx.doi.org/10.1016/j.susc.2022.122237.
Kastenmeier, M.; Fusek, L.; Mohamed, F.; Schuschke, C.; Ronovsky, M.; Camellone, M. F.; Tsud, N.; Johanek, V.; Fabris, S.; Piccinin, S.; Myslivec, J.; Brummel, O.; Lykhach, Y.; Skala, T.; Libuda, J., Pd/Co3O4(111) Interface Formation. J. Phys. Chem. C 2023, 127 (12), 6034-6044, https://dx.doi.org/10.1021/acs.jpcc.3c00261.
Hilpert, F.; Liao, P. C.; Franz, E.; Koch, V. M.; Fromm, L.; Topraksal, E.; Gorling, A.; Smith, A. S.; Barr, M. K. S.; Bachmann, J.; Brummel, O.; Libuda, J., Mechanistic Insight into Solution-Based Atomic Layer Deposition of CuSCN Provided by In Situ and Ex Situ Methods. ACS Appl. Mater. Interfaces 2023, 15 (15), 19536-19544, https://dx.doi.org/10.1021/acsami.2c16943.
Franz, E.; Jung, J. N.; Kunz, A.; Wegner, H. A.; Brummel, O.; Mollenhauer, D.; Libuda, J., How Adsorption Affects the Energy Release in an Azothiophene- Based Molecular Solar-Thermal System. J. Phys. Chem. Lett. 2023, https://dx.doi.org/10.1021/acs.jpclett.2c03732.
Eschenbacher, R.; Trzeciak, S.; Schuschke, C.; Schotz, S.; Hohner, C.; Blaumeiser, D.; Zahn, D.; Retzer, T.; Libuda, J., Thermal Stability and CO Permeability of C(4)C(1)Pyr NTf2 /Pd(111) Model SCILLs: from UHV to Ambient Pressure. Top Catal 66, 1202–1216 (2023), https://dx.doi.org/10.1007/s11244-023-01798-4.
Yang, T.; Yang, J.; Deng, X.; Franz, E.; Fromm, L.; Taccardi, N.; Liu, Z.; Gorling, A.; Wasserscheid, P.; Brummel, O.; Libuda, J., Modifying the Electrocatalytic Selectivity of Oxidation Reactions with Ionic Liquids. Angew Chem Int Ed Engl 2022, 61 (29), e202202957, https://dx.doi.org/10.1002/anie.202202957.
Wolf, P.; Wick, C. R.; Mehler, J.; Blaumeiser, D.; Schotz, S.; Bauer, T.; Libuda, J.; Smith, D.; Smith, A. S.; Haumann, M., Improving the Performance of Supported Ionic Liquid Phase Catalysts for the Ultra-Low-Temperature Water Gas Shift Reaction Using Organic Salt Additives. ACS Catal 2022, 12 (9), 5661-5672, https://dx.doi.org/10.1021/acscatal.1c05979.
Wiegmann, T.; Pacheco, I.; Reikowski, F.; Stettner, J.; Qiu, C.; Bouvier, M.; Bertram, M.; Faisal, F.; Brummel, O.; Libuda, J.; Drnec, J.; Allongue, P.; Maroun, F.; Magnussen, O. M., Operando Identification of the Reversible Skin Layer on Co(3)O(4) as a Three-Dimensional Reaction Zone for Oxygen Evolution. ACS Catal 2022, 12 (6), 3256-3268, https://dx.doi.org/10.1021/acscatal.1c05169.
Stredansky, M.; Moro, S.; Corva, M.; Sturmeit, H.; Mischke, V.; Janas, D.; Cojocariu, I.; Jugovac, M.; Cossaro, A.; Verdini, A.; Floreano, L.; Feng, Z.; Sala, A.; Comelli, G.; Windischbacher, A.; Puschnig, P.; Hohner, C.; Kettner, M.; Libuda, J.; Cinchetti, M.; Schneider, C. M.; Feyer, V.; Vesselli, E.; Zamborlini, G., Disproportionation of Nitric Oxide at a Surface-Bound Nickel Porphyrinoid. Angew Chem Int Ed Engl 2022, 61 (20), e202201916, https://dx.doi.org/10.1002/anie.202201916.
Reichstein, J.; Schotz, S.; Macht, M.; Maisel, S.; Stockinger, N.; Collados, C. C.; Schubert, K.; Blaumeiser, D.; Wintzheimer, S.; Gorling, A.; Thommes, M.; Zahn, D.; Libuda, J.; Bauer, T.; Mandel, K., Supraparticles for Bare-Eye H-2 Indication and Monitoring: Design, Working Principle, and Molecular Mobility. Adv. Funct. Mater. 2022, 32 (22), 13, https://doi.org/10.1002/adfm.202112379.
Lykhach, Y.; Johanek, V.; Neitzel, A.; Skala, T.; Tsud, N.; Beranova, K.; Myslivecek, J.; Brummel, O.; Libuda, J., Redox-mediated C-C bond scission in alcohols adsorbed on CeO(2-x)thin films. J Phys Condens Matter 2022, 34 (19), 13, https://dx.doi.org/10.1088/1361-648X/ac5138.
Krauter, J.; Franz, E.; Waidhas, F.; Brummel, O.; Libuda, J.; Al-Shamery, K., The role of defects in the photoconversion of 2-propanol on rutile titania: Operando spectroscopy combined with elementary studies. J. Catal. 2022, 406, 134-144, https://dx.doi.org/10.1016/j.jcat.2021.12.025.
Kastenmeier, M.; Fusek, L.; Deng, X.; Skala, T.; Mehl, S.; Tsud, N.; Grau, S.; Stumm, C.; Uvarov, V.; Johanek, V.; Libuda, J.; Lykhach, Y.; Myslivec, J.; Brummel, O., Particle Size and Shape Effects in Electrochemical Environments: Pd Particles Supported on Ordered Co3O4(111) and Highly Oriented Pyrolytic Graphite. J. Phys. Chem. C 2022, 126 (30), 12870-12881, https://dx.doi.org/10.1021/acs.jpcc.2c03109.
Jacobse, L.; Schuster, R.; Pfrommer, J.; Deng, X.; Dolling, S.; Weber, T.; Gutowski, O.; Dippel, A. C.; Brummel, O.; Lykhach, Y.; Over, H.; Libuda, J.; Vonk, V.; Stierle, A., A combined rotating disk electrode-surface x-ray diffraction setup for surface structure characterization in electrocatalysis. Rev Sci Instrum 2022, 93 (6), 065111, https://dx.doi.org/10.1063/5.0087864.
Fusek, L.; Kastenmeier, M.; Franz, E.; Fromm, L.; Goerling, A.; Brummel, O.; Libuda, J., Anchoring of porphyrins on atomically defined cobalt oxide: In-situ infrared spectroscopy at the electrified solid/liquid interface. Surf. Sci. 2022, 718, 7, https://doi.org/10.1002/adfm.202112379.
Franz, E.; Stumm, C.; Waidhas, F.; Bertram, M.; Jevric, M.; Orrego-Hernández, J.; Hölzel, H.; Moth-Poulsen, K.; Brummel, O.; Libuda, J., Tunable Energy Release in a Reversible Molecular Solar Thermal System. ACS Catal. 2022, 12 (21), 13418-13425, https://dx.doi.org/10.1021/acscatal.2c03043.
Franz, E.; Kunz, A.; Oberhof, N.; Heindl, A. H.; Bertram, M.; Fusek, L.; Taccardi, N.; Wasserscheid, P.; Dreuw, A.; Wegner, H. A.; Brummel, O.; Libuda, J., Electrochemically Triggered Energy Release from an Azothiophene-Based Molecular Solar Thermal System. ChemSusChem 2022, 15 (18), e202200958, https://dx.doi.org/10.1002/cssc.202200958.
Franz, E.; Krappmann, D.; Fromm, L.; Luchs, T.; Gorling, A.; Hirsch, A.; Brummel, O.; Libuda, J., Electrocatalytic Energy Release of Norbornadiene-Based Molecular Solar Thermal Systems: Tuning the Electrochemical Stability by Molecular Design. ChemSusChem 2022, 15 (24), e202201483, https://dx.doi.org/10.1002/cssc.202201483.
Fickenscher, G.; Fromm, L.; Gorling, A.; Libuda, J., Atomic Layer Deposition of HfS2 on Oxide Interfaces: A Model Study on the Initial Nucleation Processes. J. Phys. Chem. C 2022, 10, https://dx.doi.org/10.1021/acs.jpcc.2c06293.
Eschenbacher, R.; Xu, T.; Franz, E.; Low, R.; Moje, T.; Fromm, L.; Gorling, A.; Brummel, O.; Herges, R.; Libuda, J., Triggering the energy release in molecular solar thermal systems: Norbornadiene-functionalized trioxatriangulen on Au(111). Nano Energy 2022, 95, 11, https://dx.doi.org/ARTN 10700710.1016/j.nanoen.2022.107007.
Buhlmeyer, H.; Adamsen, K. C.; Xu, T.; Lammich, L.; Libuda, J.; Lauritsen, J. V.; Wendt, S., Adsorption and Reaction of NH(3)on Rutile TiO2(110): An STM Study. J. Phys. Chem. C 2022, 126 (15), 6590-6600, https://dx.doi.org/10.1021/acs.jpcc.2c01414.
Brummel, O.; Lykhach, Y.; Ralaiarisoa, M.; Berasategui, M.; Kastenmeier, M.; Fusek, L.; Simanenko, A.; Gu, W.; Clark, P. C. J.; Yivlialin, R.; Sear, M. J.; Myslivecek, J.; Favaro, M.; Starr, D. E.; Libuda, J., A Versatile Approach to Electrochemical In Situ Ambient-Pressure X-ray Photoelectron Spectroscopy: Application to a Complex Model Catalyst. J Phys Chem Lett 2022, 13 (47), 11015-11022, https://dx.doi.org/10.1021/acs.jpclett.2c03004.
Bezkrovnyi, O.; Bruix, A.; Blaumeiser, D.; Piliai, L.; Schotz, S.; Bauer, T.; Khalakhan, I.; Skala, T.; Matvija, P.; Kraszkiewicz, P.; Pawlyta, M.; Vorokhta, M.; Matolinova, I.; Libuda, J.; Neyman, K. M.; Kepinski, L., Metal-Support Interaction and Charge Distribution in Ceria-Supported Au Particles Exposed to CO. Chem Mater 2022, 34 (17), 7916-7936, https://dx.doi.org/10.1021/acs.chemmater.2c01659.
Yang, T.; Kastenmeier, M.; Ronovsky, M.; Fusek, L.; Skala, T.; Waidhas, F.; Bertram, M.; Tsud, N.; Matvija, P.; Prince, K. C.; Matolin, V.; Liu, Z.; Johanek, V.; Myslivecek, J.; Lykhach, Y.; Brummel, O.; Libuda, J., Selective electrooxidation of 2-propanol on Pt nanoparticles supported on Co3O4: an in-situ study on atomically defined model systems. J. Phys. D-Appl. Phys. 2021, 54 (16), 14, https://iopscience.iop.org/article/10.1088/1361-6463/abd9ea.
Wang, Z. H.; Erhart, P.; Li, T.; Zhang, Z. Y.; Sampedro, D.; Hu, Z. Y.; Wegner, H. A.; Brummel, O.; Libuda, J.; Nielsen, M. B.; Moth-Poulsen, K., Storing energy with molecular photoisomers. Joule 2021, 5 (12), 3116-3136, https://dx.doi.org/10.1016/j.joule.2021.11.001.
Sturmeit, H. M.; Cojocariu, I.; Windischbacher, A.; Puschnig, P.; Piamonteze, C.; Jugovac, M.; Sala, A.; Africh, C.; Comelli, G.; Cossaro, A.; Verdini, A.; Floreano, L.; Stredansky, M.; Vesselli, E.; Hohner, C.; Kettner, M.; Libuda, J.; Schneider, C. M.; Zamborlini, G.; Cinchetti, M.; Feyer, V., Room-Temperature On-Spin-Switching and Tuning in a Porphyrin-Based Multifunctional Interface. Small 2021, 17 (50), e2104779, https://dx.doi.org/10.1002/smll.202104779.
Stumm, C.; Kastenmeier, M.; Waidhas, F.; Bertram, M.; Sandbeck, D. J. S.; Bochmann, S.; Mayrhofer, K. J. J.; Bachmann, J.; Cherevko, S.; Brummel, O.; Libuda, J., Model electrocatalysts for the oxidation of rechargeable electrofuels – carbon supported Pt nanoparticles prepared in UHV. Electrochim. Acta 2021, 389, 13, https://doi.org/10.1016/j.electacta.2021.138716.
Stumm, C.; Grau, S.; Speck, F. D.; Hilpert, F.; Briega-Martos, V.; Mayrhofer, K.; Cherevko, S.; Brummel, O.; Libuda, J., Reduction of Oxide Layers on Au(111): The Interplay between Reduction Rate, Dissolution, and Restructuring. J. Phys. Chem. C 2021, 125 (41), 22698-22704, https://dx.doi.org/10.1021/acs.jpcc.1c03969.
Stumm, C.; Bertram, M.; Kastenmeier, M.; Speck, F. D.; Sun, Z. Z.; Rodriguez-Fernandez, J.; Lauritsen, J. V.; Mayrhofer, K. J. J.; Cherevko, S.; Brummel, O.; Libuda, J., Structural Dynamics of Ultrathin Cobalt Oxide Nanoislands under Potential Control. Adv. Funct. Mater. 2021, 31 (13), 13, https://doi.org/10.1002/adfm.202009923.
Schuster, R.; Wahler, T.; Kettner, M.; Agel, F.; Bauer, T.; Wasserscheid, P.; Libuda, J., Model Studies on the Ozone-Mediated Synthesis of Cobalt Oxide Nanoparticles from Dicobalt Octacarbonyl in Ionic Liquids. ChemistryOpen 2021, 10 (2), 141-152, https://dx.doi.org/10.1002/open.202000187.
Schuster, R.; Bertram, M.; Runge, H.; Geile, S.; Chung, S.; Vonk, V.; Noei, H.; Poulain, A.; Lykhach, Y.; Stierle, A.; Libuda, J., Metastability of palladium carbide nanoparticles during hydrogen release from liquid organic hydrogen carriers. Phys Chem Chem Phys 2021, 23 (2), 1371-1380, https://dx.doi.org/10.1039/d0cp05606e.
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Amende, M.; Gleichweit, C.; Xu, T.; Hofert, O.; Koch, M.; Wasserscheid, P.; Steinruck, H. P.; Papp, C.; Libuda, J., Dicyclohexylmethane as a Liquid Organic Hydrogen Carrier: A Model Study on the Dehydrogenation Mechanism over Pd(111). Catal. Lett. 2016, 146 (4), 851-860, https://dx.doi.org/10.1007/s10562-016-1711-z.
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Schernich, S.; Wagner, V.; Taccardi, N.; Wasserscheid, P.; Laurin, M.; Libuda, J., Interface controls spontaneous crystallization in thin films of the ionic liquid [C(2)C(1)Im][OTf] on atomically clean Pd(111). Langmuir 2014, 30 (23), 6846-51, https://dx.doi.org/10.1021/la500842c.
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Rockert, M.; Franke, M.; Tariq, Q.; Lungerich, D.; Jux, N.; Stark, M.; Kaftan, A.; Ditze, S.; Marbach, H.; Laurin, M.; Libuda, J.; Steinruck, H. P.; Lytken, O., Insights in Reaction Mechanistics: Isotopic Exchange during the Metalation of Deuterated Tetraphenyl-21,23D-porphyrin on Cu(111). J. Phys. Chem. C 2014, 118 (46), 26729-26736, https://dx.doi.org/10.1021/jp507303h.
Papp, C.; Wasserscheid, P.; Libuda, J.; Steinruck, H. P., Liquid organic hydrogen carriers: surface science studies of carbazole derivatives. Chem Rec 2014, 14 (5), 879-96, https://dx.doi.org/10.1002/tcr.201402014.
Neitzel, A.; Lykhach, Y.; Skala, T.; Tsud, N.; Vorokhta, M.; Mazur, D.; Prince, K. C.; Matolin, V.; Libuda, J., Surface sites on Pt-CeO2 mixed oxide catalysts probed by CO adsorption: a synchrotron radiation photoelectron spectroscopy study. Phys Chem Chem Phys 2014, 16 (45), 24747-54, https://dx.doi.org/10.1039/c4cp03346a.
Neitzel, A.; Lykhach, Y.; Skala, T.; Tsud, N.; Johanek, V.; Vorokhta, M.; Prince, K. C.; Matolin, V.; Libuda, J., Hydrogen activation on Pt-Sn nanoalloys supported on mixed Sn-Ce oxide films. Phys Chem Chem Phys 2014, 16 (26), 13209-19, https://dx.doi.org/10.1039/c4cp01632g.
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Lykhach, Y.; Neitzel, A.; Sevcikova, K.; Johanek, V.; Tsud, N.; Skala, T.; Prince, K. C.; Matolin, V.; Libuda, J., The mechanism of hydrocarbon oxygenate reforming: C-C bond scission, carbon formation, and noble-metal-free oxide catalysts. ChemSusChem 2014, 7 (1), 77-81, https://dx.doi.org/10.1002/cssc.201301000.
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Óvári, L.; Krick Calderon, S.; Lykhach, Y.; Libuda, J.; Erdőhelyi, A.; Papp, C.; Kiss, J.; Steinrück, H. P., Near ambient pressure XPS investigation of the interaction of ethanol with Co/CeO2(111). J. Catal. 2013, 307, 132-139, https://dx.doi.org/10.1016/j.jcat.2013.07.015.
Lykhach, Y.; Happel, M.; Johanek, V.; Skala, T.; Kollhoff, F.; Tsud, N.; Dvorak, F.; Prince, K. C.; Matolin, V.; Libuda, J., Adsorption and Decomposition of Formic Acid on Model Ceria and Pt/Ceria Catalysts. J. Phys. Chem. C 2013, 117 (24), 12483-12494, https://dx.doi.org/10.1021/jp311008v.
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Freund, H. J.; Libuda, J.; Baumer, M.; Risse, T.; Carlsson, A., Cluster, facets, and edges: site-dependent selective chemistry on model catalysts. Chem Rec 2003, 3 (3), 181-201, https://dx.doi.org/10.1002/tcr.10060.
Freund, H. J.; Baumer, M.; Libuda, J.; Risse, T.; Rupprechter, G.; Shaikhutdinov, S., Preparation and characterization of model catalysts: from ultrahigh vacuum to in situ conditions at the atomic dimension. J. Catal. 2003, 216 (1-2), 223-235, https://dx.doi.org/10.1016/S0021-9517(02)00073-8.
Shaikhutdinov, S.; Heemeier, M.; Hoffmann, J.; Meusel, I.; Richter, B.; Baumer, M.; Kuhlenbeck, H.; Libuda, J.; Freund, H. J.; Oldman, R.; Jackson, S. D.; Konvicka, C.; Schmid, M.; Varga, P., Interaction of oxygen with palladium deposited on a thin alumina film. Surf. Sci. 2002, 501 (3), 270-281, https://doi.org/10.1016/S0039-6028(01)01850-7.
Schauermann, S.; Hoffmann, J.; Johanek, V.; Hartmann, J.; Libuda, J.; Freund, H. J., The molecular origins of selectivity in methanol decomposition on Pd nanoparticles. Catal. Lett. 2002, 84 (3-4), 209-217, https://dx.doi.org/Doi 10.1023/A:1021484121334.
Schauermann, S.; Hoffmann, J.; Johanek, V.; Hartmann, J.; Libuda, J.; Freund, H. J., Catalytic activity and poisoning of specific sites on supported metal nanoparticles. Angew Chem Int Ed Engl 2002, 41 (14), 2532-5, https://dx.doi.org/10.1002/1521-3773(20020715)41:14<2532::AID-ANIE2532>3.0.CO;2-3.
Schauermann, S.; Hoffmann, J.; Johanek, V.; Hartmann, J.; Libuda, J., Adsorption, decomposition and oxidation of methanol on alumina supported palladium particles. Phys. Chem. Chem. Phys. 2002, 4 (15), 3909-3918, https://dx.doi.org/10.1039/b203250n.
Libuda, J.; Freund, H. J., Reaction kinetics on complex model catalysts under single scattering conditions. J. Phys. Chem. B 2002, 106 (19), 4901-4915, https://dx.doi.org/10.1021/jp014055e.
Hoffmann, J.; Schauermann, S.; Hartmann, J.; Zhdanov, V. P.; Kasemo, B.; Libuda, J.; Freund, H. J., Nanofacet-resolved CO oxidation kinetics on alumina- supported Pd particles. Chem. Phys. Lett. 2002, 354 (5-6), 403-408, https://doi.org/10.1016/S0009-2614(02)00151-3
Meusel, I.; Hoffmann, J.; Hartmann, J.; Libuda, J.; Freund, H. J., Size dependent reaction kinetics on supported model catalysts: A molecular beam/IRAS study of the CO oxidation on alumina-supported Pd particles. J. Phys. Chem. B 2001, 105 (17), 3567-3576, https://dx.doi.org/10.1021/jp003601l.
Meusel, I.; Hoffmann, J.; Hartmann, J.; Heemeier, M.; Baumer, M.; Libuda, J.; Freund, H. J., The interaction of oxygen with alumina-supported palladium particles. Catal. Lett. 2001, 71 (1-2), 5-13, https://link.springer.com/article/10.1023/A:1016635804185
Libuda, J.; Meusel, I.; Hoffmann, J.; Hartmann, J.; Piccolo, L.; Henry, C. R.; Freund, H. J., The CO oxidation kinetics on supported Pd model catalysts: A molecular beam/in situ time-resolved infrared reflection absorption spectroscopy study. J. Chem. Phys. 2001, 114 (10), 4669-4684, https://dx.doi.org/Doi 10.1063/1.1342240.
Libuda, J.; Meusel, I.; Hoffmann, J.; Hartmann, J.; Freund, H. J., Reaction kinetics on supported model catalysts: Molecular beam/in situ time-resolved infrared reflection absorption spectroscopy study of the CO oxidation on alumina supported Pd particles. J. Vac. Sci. Technol. A 2001, 19 (4), 1516-1523, https://dx.doi.org/Doi 10.1116/1.1345910.
Hoffmann, J.; Meusel, I.; Hartmann, J.; Libuda, J.; Freund, H. J., Reaction kinetics on heterogeneous model catalysts – The CO oxidation on alumina-supported Pd particles. J. Catal. 2001, 204 (2), 378-392, https://dx.doi.org/10.1006/jcat.2001.3374.
Freund, H. J.; Kuhlenbeck, H.; Libuda, J.; Rupprechter, G.; Baumer, M.; Hamann, H., Bridging the pressure and materials gaps between catalysis and surface science: clean and modified oxide surfaces. Top. Catal. 2001, 15 (2-4), 201-209, https://dx.doi.org/Doi 10.1023/A:1016686322301.
Libuda, J.; Scoles, G., Collision-induced desorption of hydrocarbons physisorbed on Au(111). J. Chem. Phys. 2000, 112 (3), 1522-1530, https://dx.doi.org/Doi 10.1063/1.480698.
Libuda, J.; Meusel, I.; Hartmann, J.; Freund, H. J., A molecular beam/surface spectroscopy apparatus for the study of reactions on complex model catalysts. Rev. Sci. Instrum. 2000, 71 (12), 4395-4408, https://doi.org/10.1063/1.1318919
Heemeier, M.; Frank, M.; Libuda, J.; Wolter, K.; Kuhlenbeck, H.; Baumer, M.; Freund, H. J., The influence of OH groups on the growth of rhodium on alumina: a model study. Catal. Lett. 2000, 68 (1-2), 19-24, https://dx.doi.org/Doi 10.1023/A:1019058714724.
Dellwig, T.; Hartmann, J.; Libuda, J.; Meusel, I.; Rupprechter, G.; Unterhalt, H.; Freund, H. J., Complex model catalysts under UHV and high pressure conditions: CO adsorption and oxidation on alumina-supported Pd particles. J. Mol. Catal. A-Chem. 2000, 162 (1-2), 51-66, https://dx.doi.org/Doi 10.1016/S1381-1169(00)00321-6.
Libuda, J.; Scoles, G., Collision-induced chemical dynamics in ethanethiol adsorbed on Au(111). J. Phys. Chem. B 1999, 103 (45), 9933-9943, https://doi.org/10.1021/jp9917493.
Frank, M.; Andersson, S.; Libuda, J.; Stempel, S.; Sandell, A.; Brena, B.; Giertz, A.; Bruhwiler, P. A.; Baumer, M.; Martensson, N.; Freund, H. J., Particle size dependent CO dissociation on alumina-supported Rh: a model study (vol 279, pg 92, 1997). Chem. Phys. Lett. 1999, 310 (1-2), 229-230, https://doi.org/10.1016/S0009-2614(97)01114-7.
Andersson, S.; Bruhwiler, P. A.; Sandell, A.; Frank, M.; Libuda, J.; Giertz, A.; Brena, B.; Maxwell, A. J.; Baumer, M.; Freund, H. J.; Martensson, N., Metal-oxide interaction for metal clusters on a metal-supported thin alumina film. Surf. Sci. 1999, 442 (1), L964-L970, https://dx.doi.org/Doi 10.1016/S0039-6028(99)00915-2.
Wolter, K.; Seiferth, O.; Libuda, J.; Kuhlenbeck, H.; Baumer, M.; Freund, H. J., Infrared study of CO adsorption on alumina supported palladium particles. Surf. Sci. 1998, 402 (1-3), 428-432, https://dx.doi.org/Doi 10.1016/S0039-6028(97)01053-4.
Sandell, A.; Beutler, A.; Nyholm, R.; Andersen, J. N.; Andersson, S.; Bruhwiler, P. A.; Martensson, N.; Libuda, J.; Wolter, K.; Seiferth, O.; Baumer, M.; Kuhlenbeck, H.; Freund, H. J., Observation of a low-energy adsorbate core-level satellite for CO bonded to palladium: Coordination-dependent effects. Phys. Rev. B 1998, 57 (20), 13199-13208, https://dx.doi.org/DOI 10.1103/PhysRevB.57.13199.
Freund, H. J.; Baumer, M.; Libuda, J.; Kuhlenbeck, H.; Risse, T.; Al-Shamery, K.; Hamann, H., Metal aggregates on oxide surfaces: Structure and adsorption. Cryst. Res. Technol. 1998, 33 (7-8), 977-1008, https://doi.org/10.1002/(SICI)1521-4079(199810)33:7/8<977::AID-CRAT977>3.0.CO;2-M.
Andersson, S.; Frank, M.; Sandell, A.; Libuda, J.; Brena, B.; Giertz, A.; Bruhwiler, P. A.; Baumer, M.; Martensson, N.; Freund, H. J., Temperature dependent XPS study of CO dissociation on small Rh particles. Vacuum 1998, 49 (3), 167-170, https://dx.doi.org/Doi 10.1016/S0042-207x(97)00172-3.
Andersson, S.; Frank, M.; Sandell, A.; Giertz, A.; Brena, B.; Bruhwiler, P. A.; Martensson, N.; Libuda, J.; Baumer, M.; Freund, H. J., CO dissociation characteristics on size-distributed rhodium islands on alumina model substrates. J. Chem. Phys. 1998, 108 (7), 2967-2974, https://dx.doi.org/Doi 10.1063/1.475684.
Wolter, K.; Seiferth, O.; Libuda, J.; Kuhlenbeck, H.; Baumer, M.; Freund, H. J., IR spectroscopy of a Pd-carbonyl surface compound. Chem. Phys. Lett. 1997, 277 (5-6), 513-520, https://dx.doi.org/Doi 10.1016/S0009-2614(97)00956-1.
Sandell, A.; Libuda, J.; Bruhwiler, P. A.; Andersson, S.; Baumer, M.; Maxwell, A. J.; Martensson, N.; Freund, H. J., Transition from a molecular to a metallic adsorbate system: Core-hole creation and decay dynamics for CO coordinated to Pd. Phys. Rev. B 1997, 55 (11), 7233-7243, https://dx.doi.org/DOI 10.1103/PhysRevB.55.7233.
Libuda, J.; Frank, M.; Sandell, A.; Andersson, S.; Bruhwiler, P. A.; Baumer, M.; Martensson, N.; Freund, H. J., Interaction of rhodium with hydroxylated alumina model substrates. Surf. Sci. 1997, 384 (1-3), 106-119, https://dx.doi.org/Doi 10.1016/S0039-6028(97)00170-2.
Frank, M.; Andersson, S.; Libuda, J.; Stempel, S.; Sandell, A.; Brena, B.; Giertz, A.; Bruhwiler, P. A.; Baumer, M.; Martensson, N.; Freund, H. J., Particle size dependent CO dissociation on alumina-supported Rh: a model study. Chem. Phys. Lett. 1997, 279 (1-2), 92-99, https://dx.doi.org/Doi 10.1016/S0009-2614(97)01114-7.
Baumer, M.; Frank, M.; Libuda, J.; Stempel, S.; Freund, H. J., Growth and morphology of Rh deposits on an alumina film under UHV conditions and under the influence of CO. Surf. Sci. 1997, 391 (1-3), 204-215, https://dx.doi.org/Doi 10.1016/S0039-6028(97)00484-6.
Sandell, A.; Libuda, J.; Bruhwiler, P. A.; Andersson, S.; Maxwell, A. J.; Baumer, M.; Martensson, N.; Freund, H. J., Interaction of CO with Pd clusters supported on a thin alumina film. J. Vac. Sci. Technol. A-Vac. Surf. Films 1996, 14 (3), 1546-1551, https://dx.doi.org/Doi 10.1116/1.580293.
Sandell, A.; Libuda, J.; Baumer, M.; Freund, H. J., Metal deposition in adsorbate atmosphere: Growth and decomposition of a palladium carbonyl-like species. Surf. Sci. 1996, 346 (1-3), 108-126, https://dx.doi.org/Doi 10.1016/0039-6028(95)00912-4.
Sandell, A.; Libuda, J.; Bruhwiler, P.; Andersson, S.; Maxwell, A.; Baumer, M.; Martensson, N.; Freund, H. J., Electron spectroscopy studies of small deposited metal particles. J. Electron Spectrosc. Relat. Phenom. 1995, 76, 301-306, https://dx.doi.org/Doi 10.1016/0368-2048(95)02422-0.
Libuda, J.; Sandell, A.; Baumer, M.; Freund, H. J., Evidence for Pd-X(Co)(Y) Compound Formation on an Alumina Substrate. Chem. Phys. Lett. 1995, 240 (5-6), 429-434, https://dx.doi.org/Doi 10.1016/0009-2614(95)00555-I.
Baumer, M.; Libuda, J.; Sandell, A.; Freund, H. J.; Graw, G.; Bertrams, T.; Neddermeyer, H., The Growth and Properties of Pd and Pt on Al2o3/Nial(110). Ber. Bunsen-Ges. Phys. Chem. Chem. Phys. 1995, 99 (11), 1381-1386, https://dx.doi.org/DOI 10.1002/bbpc.199500089.
Baumer, M.; Libuda, J.; Freund, H. J., The Temperature-Dependent Growth Mode of Nickel on the Basal-Plane of Graphite. Surf. Sci. 1995, 327 (3), 321-329, https://dx.doi.org/Doi 10.1016/0039-6028(94)00855-8.
Winkelmann, F.; Wohlrab, S.; Libuda, J.; Baumer, M.; Cappus, D.; Menges, M.; Alshamery, K.; Kuhlenbeck, H.; Freund, H. J., Adsorption on Oxide Surfaces – Structure and Dynamics. Surf. Sci. 1994, 307, 1148-1160, https://dx.doi.org/Doi 10.1016/0039-6028(94)91556-3.
Rohr, F.; Wirth, K.; Libuda, J.; Cappus, D.; Baumer, M.; Freund, H. J., Hydroxyl Driven Reconstruction of the Polar Nio(111) Surface. Surf. Sci. 1994, 315 (1-2), L977-L982, https://dx.doi.org/Doi 10.1016/0039-6028(94)90529-0.
Libuda, J.; Winkelmann, F.; Baumer, M.; Freund, H. J.; Bertrams, T.; Neddermeyer, H.; Muller, K., Structure and Defects of an Ordered Alumina Film on Nial(110). Surf. Sci. 1994, 318 (1-2), 61-73, https://dx.doi.org/Doi 10.1016/0039-6028(94)90341-7.
Libuda, J.; Baumer, M.; Freund, H. J., Structural Characterization of Platinum Deposits Supported on Ordered Alumina Films. J. Vac. Sci. Technol. A-Vac. Surf. Films 1994, 12 (4), 2259-2264, https://dx.doi.org/Doi 10.1116/1.579126.
Cappus, D.; Menges, M.; Xu, C.; Ehrlich, D.; Dillmann, B.; Ventrice, C. A.; Libuda, J.; Baumer, M.; Wohlrab, S.; Winkelmann, F.; Kuhlenbeck, H.; Freund, H. J., Electronic and Geometric Structure of Adsorbates on Oxide Surfaces. J. Electron Spectrosc. Relat. Phenom. 1994, 68, 347-355, https://dx.doi.org/Doi 10.1016/0368-2048(94)02133-3.
Jaeger, R. M.; Libuda, J.; Baumer, M.; Homann, K.; Kuhlenbeck, H.; Freund, H. J., Vibrational Structure of Excited-States of Molecules on Oxide Surfaces. J. Electron Spectrosc. Relat. Phenom. 1993, 64-5, 217-225, https://dx.doi.org/Doi 10.1016/0368-2048(93)80082-W.